Styrene Monomer SDS (Safety Data Sheet)

SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Styrene Monomer

Flinn Scientific, Inc. P.O. Box 219, Batavia, IL 60510 (800) 452-1261
Chemtrec Emergency Phone Number: (800) 424-10397

Signal Word
WARNING

Hazard class: Flammable liquids (Category 3). Flammable liquid and vapor (H226). Keep away from heat, sparks, open flames, and hot surfaces. No smoking (P210).

Hazard class: Acute toxicity, oral (Category 5). May be harmful if swallowed (H303).

Hazard class: Skin and serious eye damage, corrosion or irritation (Category 2, 2A). Causes skin and serious eye irritation (H315+H319).

Hazard class: Acute toxicity, inhalation (Category 4). Harmful if inhaled (H332). Avoid breathing gas, mist, vapors or spray (P261).

Pictograms

SECTION 3 — COMPOSITION, INFORMATION ON INGREDIENTS

Component Name	CAS Number	Formula	Formula Weight	Concentration
Styrene, monomer Synonyms: Vinylbenzene	100-42-5	C₈H₈	104.15

SECTION 4 — FIRST AID MEASURES

Call a POISON CENTER or physician if you feel unwell (P312).
If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing (P304+P340).
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do so. Continue rinsing (P305+P351+P338). If eye irritation persists eyes: Get medical advice or attention (P337+P313).
If on skin or hair: Immediately remove all contaminated clothing. Rinse skin with water (P303+P361+P353).
If swallowed: Rinse mouth. Call a POISON CENTER or physician if you feel unwell.

SECTION 5 — FIRE FIGHTING MEASURES

Class IC flammable liquid.
Flash point: 31 °F Flammable limits: Lower: 0.9% Upper: 6.8% Autoignition Temperature: 490 °C
In case of fire: Use a tri-class dry chemical fire extinguisher (P370+P378).

NFPA Code

H-2
F-3
R-2

SECTION 6 — ACCIDENTAL RELEASE MEASURES

Remove all ignition sources and ventilate area. Contain spill with sand or other inert absorbent material; deposit in sealed bag or container. See Sections 8 and 13 for further information.

SECTION 7 — HANDLING AND STORAGE

Flinn Suggested Chemical Storage Pattern: Organic #3. Store with hydrocarbons, oils, esters and aldehydes.
Store in a dedicated flammables cabinet. If a flammables cabinet is not available, store in Flinn Saf-Stor™ can.
Keep container tightly closed (P233). Keep cool (P235). Ground or bond container and receiving equipment (P240). Use explosion-proof electrical and ventilating equipment (P241). Use only in a hood or well-ventilated area (P271).

SECTION 8 — EXPOSURE CONTROLS, PERSONAL PROTECTION

Wear protective gloves, protective clothing, and eye protection (P280). Wash hands thoroughly after handling (P264). Use only in a hood or well-ventilated area (P271).
Exposure guidelines: PEL 100 ppm, Ceiling 200 ppm (OSHA), TLV 20 ppm, STEL 40 ppm (ACGIH)

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

Colorless to yellowish liquid. Penetrating aromatic odor.
Soluble: Alcohol and ether. Insoluble in water.

Boiling point: 145 to 146 °C
Melting point: to 31 °C
Specific gravity: 0.909
Vapor density: 3.6

SECTION 10 — STABILITY AND REACTIVITY

Avoid contact with oxidizers, copper, copper alloys, heat, open flame, or any source of ignition.
Shelf life: Fair to poor, polymerizes. See Section 7 for further information.

SECTION 11 — TOXICOLOGICAL INFORMATION

Acute effects: Toxic, irritant, lachrymator, nausea, headache.
Chronic effects: CNS depression, dermatitis, known carcinogen, mutagen.
Target organs: N.A.

ORL-RAT LD₅₀: 2650 mg/kg
IHL-RAT LC₅₀: 24 g/m3/4H
SKN-RBT LD₅₀: N.A.

SECTION 12 — ECOLOGICAL INFORMATION

Data not yet available.

SECTION 13 — DISPOSAL CONSIDERATIONS

Please review all federal, state and local regulations that may apply before proceeding.
Flinn Suggested Disposal Method #18b is one option.

SECTION 14 — TRANSPORT INFORMATION

Shipping name: Styrene monomer, inhibited; Hazard class: 3, Flammable liquid; UN number: UN2055

SECTION 15 — REGULATORY INFORMATION

TSCA-listed, EINECS-listed (202-851-5). RCRA code D001.

SECTION 16 — OTHER INFORMATION

This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. Flinn Scientific, Inc. makes no guarantee of the accuracy or completeness of the data and shall not be liable for any damages relating thereto. The data is offered solely for your consideration, investigation, and verification. The data should not be confused with local, state, federal or insurance mandates, regulations, or requirements and CONSTITUTE NO WARRANTY. Any use of this data and information must be determined by the science instructor to be in accordance with applicable local, state or federal laws and regulations. The conditions or methods of handling, storage, use and disposal of the product(s) described are beyond the control of Flinn Scientific, Inc. and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THIS PRODUCT(S).

Consult your copy of the Flinn Science Catalog/Reference Manual for additional information about laboratory chemicals.

Styrene Monomer Safety Data Sheet (SDS)

Styrene Monomer